RT info:eu-repo/semantics/article T1 Physicochemical analysis of Catonyx cuvieri (Mammalia, Xenarthra) remains from the Pleistocene of Paraguay A1 Sanabria, Bella A1 Colmán Patiño, Christian Fernando A1 Aquino Ayala, Celeste Zunilda A1 Miño Boilini, Ángel Ramón A1 Zurita, Alfredo Eduardo A1 Souberlich Barúa, Ricardo Froilan A1 Ríos, Sergio Daniel A1 Méndez, Fernando José A1 Matos da Silva Costa, Alex A1 Herrera, Edher Zacarias A2 Universidad Nacional de Asunción. Facultad de Ciencias Exactas y Naturales AB The fossil-diagenetic characteristics, such as mineralogical aspects present in the ribs of Catonyx cuvieri (Lund, 1839) (Mammalia, Xenarthra), were analyzed in this work. These analyzed remains come from the Risso Cave, San Lazaro's District, Concepción Department, Paraguay. The vibrational response was studied using Raman and Fourier transform infrared (FTIR) and the mineralogy and elemental compositions were examined using multiple characterizations techniques. The main functional groups belong to the mineral part of the bone, and specific functional groups were associated with organic components. The characterization indicated that material was composed of apatites and the original mineral structure was affected by partial ionic substitutions, probably due to the interaction of the fossil with the environment. A Gaussian deconvolution model (GM) was used to identify the individual overlapping bands in the regions of interest in the spectra. A diagenesis pathway for the fossil involved the inclusion of calcium carbonate on the surface of the bone due to the accumulation of moisture, which allowed the recrystallization of hydroxyapatite and the precipitation of calcite in the pores and silicates of the bone. It’s worth mentioning that this work is the first in the ground sloths C. cuvieri in South America. In addition, the material here constitutes the most complete fossil record of a member of the Pleistocene megafaunal of Paraguay. PB Elsevier B.V. YR 2024 FD 2024-08-30 LK http://hdl.handle.net/20.500.14066/4483 UL http://hdl.handle.net/20.500.14066/4483 LA eng NO Sanabria, B., Colman, C. F., Aquino, C., Miño Boilini, Á. R., Zurita, A. E., Souberlich, R., Ríos, S. D., Méndez, F., Matos da Silva Costa, A., & Herrera, E. Z. (2024). Physicochemical analysis of Catonyx cuvieri (Mammalia, Xenarthra) remains from the Pleistocene of Paraguay. Results in Chemistry, 10, Artículo 101745.https://doi.org/10.1016/j.rechem.2024.101745 NO Corresponding author at: edher@facen.una.py, E.Z. Herrera. Facultad de Ciencias Exactas y Naturales, San Lorenzo, Paraguay NO Consejo Nacional de Ciencia y Tecnología DS MINDS@UW RD 19-dic-2024